2-{4-[(Quinolin-8-yloxy)methyl]phenyl}benzonitrile
نویسنده
چکیده
In the title compound, C(23)H(16)N(2)O, the bond angle at the O atom that connects the benzene ring and the quinoline ring system is 116.0 (2)°. The quinoline ring system make a dihedral angle of 16.5 (2)° with the adjacent benzene ring. The dihedral angle between the biphenyl benzene rings is 70.8 (2)°.
منابع مشابه
7-[(Morpholin-4-yl)(phenyl)methyl]quinolin-8-ol
In the title compound, C20H20N2O2, the quinoline ring system makes dihedral angles of 81.05 (4) and 61.16 (5)° with the mean planes of the benzene and morpholine rings, respectively; the mean planes of the latter two rings make a dihedral angle of 83.59 (4)°. In the crystal, pairs of O-H⋯N hydrogen bonds link neighbouring mol-ecules related by a twofold rotation axis, generating R2(2)(10) motifs.
متن کامل2-[(Quinolin-8-yloxy)methyl]-1H-benzimidazole monohydrate
In the title hydrate, C17H13N3O·H2O, the dihedral angle between the quinoline and benzimidazole ring systems is 6.22 (7)°. The water mol-ecule is linked to the main mol-ecule by N-H⋯O and O-H⋯N hydrogen bonds. Further O-H⋯N hydrogen bonds link the organic molecules into C(6) chains running parallel to the b axis.
متن کاملDiiodido[methyl 2-(quinolin-8-yloxy)acetate-κN]mercury(II)
In the title mononuclear complex, [HgI(2)(C(12)H(11)NO(3))], the Hg(II) ion has a distorted trigonal-planar coordination sphere defined by two I(-) anions and the N atom of a methyl 2-(quinolin-8-yl-oxy)acetate ligand. In the crystal, face-to-face π-π stacking inter-actions, with a centroid-centroid distance of 3.563 (9) Å, are observed.
متن کاملDibromido[methyl 2-(quinolin-8-yloxy-κ2 N,O)acetic acid-κO]mercury(II)
In the title complex, [HgBr(2)(C(12)H(11)NO(3))], the Hg(II) ion has a distorted core trigonal-planar geometry comprising two Br atoms and one quinoline N atom of the methyl 2-(quinolin-8-yl-oxy)acetic acid ligand. The angles around the Hg atom vary from 100.31 (15) to 152.65 (4)°. Two additional Hg⋯O inter-actions [2.739 (1) and 2.905 (1) Å] complete the coordination sphere about the Hg(II) atom.
متن کامل2-[1-({2-[1-(2-Hydroxy-5-{[methyl(phenyl)amino]methyl}phenyl)ethylideneamino]ethyl}imino)ethyl]-4-{[methyl(phenyl)amino]methyl}phenol
Mol-ecules of the title compound, C(34)H(38)N(4)O(2), lie across crystallographic inversion centres. The crystal packing can be described by alternating zigzag chains along the c axis in which the molecules are linked by van der Waals interactions. There is an intra-molecular O-H⋯N hydrogen bond and the two benzene rings in the asymmetric unit make a dihedral angle of 79.81 (6)°.
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